Issue 5, 2009

Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives

Abstract

Kinetically controlled lithiation of 3-hexoxythiophene in the 5-position allows the synthesis of interesting functionalised building blocks after reaction with N,N-dimethylformamide and iodine.

Graphical abstract: Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives

Supplementary files

Article information

Article type
Communication
Submitted
29 Sep 2008
Accepted
03 Nov 2008
First published
02 Dec 2008

Chem. Commun., 2009, 565-567

Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives

M. J. Zöllner, U. Jahn, E. Becker, W. Kowalsky and H. Johannes, Chem. Commun., 2009, 565 DOI: 10.1039/B817089D

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