Novel ⊕N(←L)2 species with two lone pairs on nitrogen: systems isoelectronic to carbodicarbenes

Dhilon S. Patel; Prasad V. Bharatam

doi:10.1039/B816595E

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Novel ^⊕N(←L)₂ species with two lone pairs on nitrogen: systems isoelectronic to carbodicarbenes†

Dhilon S. Patel^a and Prasad V. Bharatam*^a

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* Corresponding authors

^a Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar (Mohali), Punjab, India
E-mail: pvbharatam@niper.ac.in
Fax: (+) 91-172-2214692
Tel: (+) 91-172-2214685

Abstract

A new bonding environment has been identified for nitrogen in chemical species with the general formula ^⊕N(←L)₂ (I), in which the N atom is characterized by two lone pairs.

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Supplementary files

The coordinates of the optimized geometries of 1–10 and IVa–e along with their 3D structures, absolute andrelative energies of these species PDF (2243K)

Article information

DOI: https://doi.org/10.1039/B816595E
Article type: Communication
Submitted: 22 Sep 2008
Accepted: 13 Nov 2008
First published: 05 Jan 2009

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Chem. Commun., 2009, 1064-1066

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Novel ^⊕N(←L)₂ species with two lone pairs on nitrogen: systems isoelectronic to carbodicarbenes

D. S. Patel and P. V. Bharatam, Chem. Commun., 2009, 1064 DOI: 10.1039/B816595E

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