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Issue 1, 2009
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Palladium- (and nickel-) catalyzed vinylation of aryl halides

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Abstract

Functionalized styrenes are extremely useful building blocks for organic synthesis and for functional polymers. One of the most general syntheses of styrenes involves the combination of an aryl halide with a vinyl organometallic reagent under catalysis by palladium or nickel complexes. This Feature Article provides the first comprehensive summary of the vinylation methods currently available along with a critical comparison of the efficiency, cost and scope of the methods.

Graphical abstract: Palladium- (and nickel-) catalyzed vinylation of aryl halides

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Publication details

The article was received on 10 Jun 2008, accepted on 02 Jul 2008 and first published on 27 Aug 2008


Article type: Feature Article
DOI: 10.1039/B809676G
Citation: Chem. Commun., 2009,0, 20-33

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    Palladium- (and nickel-) catalyzed vinylation of aryl halides

    S. E. Denmark and C. R. Butler, Chem. Commun., 2009, 0, 20
    DOI: 10.1039/B809676G

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