Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle

Filipa L. Sousa; Hartmut Bögge; Alice Merca; Pierre Gouzerh; René Thouvenot; Achim Müller

doi:10.1039/B917476A

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Vectorial growth/regulations in a {P₈W₄₈}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle†

Filipa L. Sousa,^a Hartmut Bögge,^a Alice Merca,^a Pierre Gouzerh,^b René Thouvenot*^b and Achim Müller*^a

Author affiliations

* Corresponding authors

^a Fakultät für Chemie, Universität Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany
E-mail: a.mueller@uni-bielefeld.de
Web: http://www.uni-bielefeld.de/chemie/ac1/
Fax: +49 521-106-6003
Tel: +49 521-106-6153

^b Institut Parisien de Chimie Moléculaire UMR 7201, Case courrier 42, Université Pierre et Marie Curie-Paris6, 4 Place Jussieu, 75252 Paris Cedex 05, France
E-mail: rene.thouvenot@upmc.fr
Fax: +33 1 44 27 38 41
Tel: +33 1 44 27 55 53

Abstract

Reaction of the cyclic {P₈W₄₈} polyoxotungstate host with sodium molybdate in solution in the presence of a reducing agent leads to the formation and stabilization of unprecedented neutral {Mo^V₄O₁₀(H₂O)₃} aggregates with handle function, thereby proving the potential of the present host for performing future interesting studies related to mixed-valence type chemistry under confined conditions.

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Supplementary files

Crystal structure data TXT (47K)

Article information

DOI: https://doi.org/10.1039/B917476A
Article type: Communication
Submitted: 25 Aug 2009
Accepted: 19 Oct 2009
First published: 09 Nov 2009

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Chem. Commun., 2009, 7491-7493

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Vectorial growth/regulations in a {P₈W₄₈}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle

F. L. Sousa, H. Bögge, A. Merca, P. Gouzerh, R. Thouvenot and A. Müller, Chem. Commun., 2009, 7491 DOI: 10.1039/B917476A

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