Issue 42, 2009
From the journal:

Chemical Communications

Oxidation of cyclic acetals by ozone in ionic liquid media

Charlie Van Doorslaer,a   Annelies Peeters,a   Pascal Mertens,a   Chris Vinckier,b   Koen Binnemansb  and  Dirk De Vos*a  

* Corresponding authors

a Centre for Surface Chemistry and Catalysis, Department of Microbial and Molecular Systems, K.U.Leuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium
E-mail: dirk.devos@biw.kuleuven.be

b Division for Molecular Design and Synthesis, Department of Chemistry, K.U. Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

Abstract

The application of ozone-stable pyrrolidinium based ionic liquids as safe reaction media resulted in selective hydroxy ester formation upon ozonation of cyclic acetals without using low temperatures or acetylating reagents.

Graphical abstract: Oxidation of cyclic acetals by ozone in ionic liquid media

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Article information

DOI
https://doi.org/10.1039/B913431J
Article type
Communication
Submitted
06 Jul 2009
Accepted
22 Aug 2009
First published
09 Sep 2009

Chem. Commun., 2009, 6439-6441

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Oxidation of cyclic acetals by ozone in ionic liquid media

C. Van Doorslaer, A. Peeters, P. Mertens, C. Vinckier, K. Binnemans and D. De Vos, Chem. Commun., 2009, 6439 DOI: 10.1039/B913431J

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