Issue 41, 2009
From the journal:

Chemical Communications

Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot†

Richard E. Mishler II,a   Ankush V. Biradar,a   Cole T. Duncan,a   Eric A. Schiff*b  and  Tewodros Asefa*a  

* Corresponding authors

a Department of Chemistry, 111 College Place, Syracuse University, Syracuse NY 13244, USA
E-mail: tasefa@syr.edu
Fax: +1-315-443-4070
Tel: +1-315-443-3360

b Department of Physics, Syracuse University, Syracuse, USA
E-mail: easchiff@syr.edu
Fax: +1-315-443-9103
Tel: +1-315-443-2566

Abstract

We report a new and simple one-pot synthetic method to produce mesoporous silica and nanoporous solid acid catalyst capable of catalyzing pinacole-pinacolone rearrangement and esterification reactions, by preparing a solvent washable phosphonated triblock copolymer template and self-assembling it in the presence of alkoxysilane.

Graphical abstract: Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot

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Article information

DOI
https://doi.org/10.1039/B913035G
Article type
Communication
Submitted
01 Jul 2009
Accepted
01 Sep 2009
First published
18 Sep 2009

Chem. Commun., 2009, 6201-6203

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Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot

R. E. Mishler II, A. V. Biradar, C. T. Duncan, E. A. Schiff and T. Asefa, Chem. Commun., 2009, 6201 DOI: 10.1039/B913035G

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