Issue 41, 2009
From the journal:

Chemical Communications

Photo-triggered J-aggregation and chiral symmetry breaking of an anionic porphyrin (TPPS) in mixed organic solvent†

Siguang Jiang,a   Li Zhanga  and  Minghua Liu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Science (BNLMS), CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, People’s Republic of China
E-mail: liumh@iccas.ac.cn
Tel: 86-10-82612655

Abstract

Although TPPS undergoes photo-bleaching in ethanol or DMSO alone, it formed J-aggregates in the mixed solvent of ethanol and DMSO under UV irradiation, and the formed J-aggregate showed chirality due to chiral-symmetry-breaking.

Graphical abstract: Photo-triggered J-aggregation and chiral symmetry breaking of an anionic porphyrin (TPPS) in mixed organic solvent

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Article information

DOI
https://doi.org/10.1039/B912825E
Article type
Communication
Submitted
29 Jun 2009
Accepted
13 Aug 2009
First published
03 Sep 2009

Chem. Commun., 2009, 6252-6254

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Photo-triggered J-aggregation and chiral symmetry breaking of an anionic porphyrin (TPPS) in mixed organic solvent

S. Jiang, L. Zhang and M. Liu, Chem. Commun., 2009, 6252 DOI: 10.1039/B912825E

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