Living polymerization of ethylene and α-olefins using a nickel α-keto-β-diimine initiator†
Abstract
A nickel α-keto-β-diimine initiator can be activated using treated methylaluminoxane (MAO) to generate active sites capable of the polymerization of
* Corresponding authors
a
Mitsubishi Chemical Center for Advanced Materials, Departments of Chemistry & Biochemistry and Materials, Institute for Polymers and Organic Solids, University of California Santa Barbara, Santa Barbara, California, USA
E-mail:
bazan@chem.ucsb.edu
Fax: 1-805-893-5270
Tel: 1-805-893-5538
b Instituto de Química, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil
A nickel α-keto-β-diimine initiator can be activated using treated methylaluminoxane (MAO) to generate active sites capable of the polymerization of
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J. D. Azoulay, Y. Schneider, G. B. Galland and G. C. Bazan, Chem. Commun., 2009, 6177 DOI: 10.1039/B912743G
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