Reversible uptake of HgCl2 in a porous coordination polymer based on the dual functions of carboxylate and thioether

Xiao-Ping Zhou; Zhengtao Xu; Matthias Zeller; Allen D. Hunter

doi:10.1039/B910265E

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Reversible uptake of HgCl₂ in a porous coordination polymer based on the dual functions of carboxylate and thioether†

Xiao-Ping Zhou,^a Zhengtao Xu,*^a Matthias Zeller^b and Allen D. Hunter^b

Author affiliations

* Corresponding authors

^a Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, P. R. China
E-mail: zhengtao@cityu.edu.hk
Fax: +852-27844679

^b Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio, USA

Abstract

Bifunctional tetrakis(methylthio)-1,4-benzenedicarboxylic acid and Pb²⁺ ions form a robust porous net featuring free-standing thioether groups that allow reversible uptake of HgCl₂.

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Article information

DOI: https://doi.org/10.1039/B910265E
Article type: Communication
Submitted: 27 May 2009
Accepted: 21 Jul 2009
First published: 05 Aug 2009

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Chem. Commun., 2009, 5439-5441

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Reversible uptake of HgCl₂ in a porous coordination polymer based on the dual functions of carboxylate and thioether

X. Zhou, Z. Xu, M. Zeller and A. D. Hunter, Chem. Commun., 2009, 5439 DOI: 10.1039/B910265E

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