Issue 32, 2009
From the journal:

Chemical Communications

An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide†

Dumitru Ghereg,ab   Sakina Ech-Cherif El Kettani,c   Mohamed Lazraq,c   Henri Ranaivonjatovo,ab   Wolfgang W. Schoeller,d   Jean Escudié*ab  and  Heinz Gornitzka*ef  

* Corresponding authors

a Université de Toulouse, UPS, LHFA, 118 route de Narbonne, Toulouse, France
E-mail: escudie@chimie.ups-tlse.fr

b CNRS, LHFA UMR 5069, Toulouse, France
Fax: +33 561558204
Tel: +33 561558347

c Laboratoire d’Ingénierie des Matériaux Organiques et Moléculaires, Faculté des Sciences Dhar El Mehraz, Université Sidi Mohamed Ben Abdellah, Fès, Morocco

d Department of Chemistry, University of California, Riverside, USA

e CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse Cedex 4, France

f Université de Toulouse, UPS, INP, LCC, F-31077 Toulouse, France
E-mail: Heinz.Gornitzka@lcc-toulouse.fr
Fax: +33 561553003
Tel: +33 561333187

Abstract

Addition of the germene Mes2Ge[double bond, length as m-dash]CR2 to 1,4-naphthoquinone yields a singular o-quinodimethane which gives Diels–Alder reactions at room temperature and reacts cleanly with oxygen to form an endoperoxide.

Graphical abstract: An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

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Article information

DOI
https://doi.org/10.1039/B910001F
Article type
Communication
Submitted
20 May 2009
Accepted
29 Jun 2009
First published
14 Jul 2009

Chem. Commun., 2009, 4821-4823

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An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

D. Ghereg, S. Ech-Cherif El Kettani, M. Lazraq, H. Ranaivonjatovo, W. W. Schoeller, J. Escudié and H. Gornitzka, Chem. Commun., 2009, 4821 DOI: 10.1039/B910001F

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