Issue 37, 2009

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

Abstract

Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.

Graphical abstract: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

Supplementary files

Article information

Article type
Communication
Submitted
18 May 2009
Accepted
03 Aug 2009
First published
18 Aug 2009

Chem. Commun., 2009, 5561-5563

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

M. Paneque, M. L. Poveda, F. Vattier, E. Alvarez and E. Carmona, Chem. Commun., 2009, 5561 DOI: 10.1039/B909837B

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