Issue 31, 2009

Tandem reactions of cis-2-acyl-1-alkynyl-1-aryl cyclopropanes tuned by gold(i) and silver(i) catalysts: efficient synthesis of pyran-fused indene cores and 2,4,6-trisubstituted phenols

Abstract

Tandem reactions of cis-2-acyl-1-alkynyl-1-aryl cyclopropanes 1 tuned by gold(I) and silver(I) catalysts are described, which afford selectively the key pyran-fused indene cores 2 and the 2,4,6-trisubstituted phenols 3 in good yields, respectively.

Graphical abstract: Tandem reactions of cis-2-acyl-1-alkynyl-1-aryl cyclopropanes tuned by gold(i) and silver(i) catalysts: efficient synthesis of pyran-fused indene cores and 2,4,6-trisubstituted phenols

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2009
Accepted
05 Jun 2009
First published
29 Jun 2009

Chem. Commun., 2009, 4726-4728

Tandem reactions of cis-2-acyl-1-alkynyl-1-aryl cyclopropanes tuned by gold(I) and silver(I) catalysts: efficient synthesis of pyran-fused indene cores and 2,4,6-trisubstituted phenols

X. Zhang, Y. Tu, Y. Jiang, Y. Zhang, C. Fan and F. Zhang, Chem. Commun., 2009, 4726 DOI: 10.1039/B909181E

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