Issue 32, 2009
From the journal:

Chemical Communications

Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)†

Danna E. Freedman,a   David M. Jenkins‡a  and  Jeffrey R. Long*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, USA
E-mail: jrlong@berkeley.edu

Abstract

Reaction of [(PY5Me2)V(MeCN)]2+ with [M(CN)6]3− (M = Cr, Mo) affords the star-like clusters [(PY5Me2)4V4M(CN)6]5+, exhibiting S = 9/2 ground states that are exceptionally well-isolated in energy.

Graphical abstract: Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

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Article information

DOI
https://doi.org/10.1039/B908736B
Article type
Communication
Submitted
07 May 2009
Accepted
23 Jun 2009
First published
14 Jul 2009

Chem. Commun., 2009, 4829-4831

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Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

D. E. Freedman, D. M. Jenkins and J. R. Long, Chem. Commun., 2009, 4829 DOI: 10.1039/B908736B

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