Issue 44, 2009
From the journal:

Chemical Communications

A calixarene-based copper-centered redox switch as a data storage prototype†

Ulrich Darbost,*a   Vanessa Penin,a   Erwann Jeanneau,a   Caroline Félix,a   Francis Vocanson,b   Christophe Bucher,c   Guy Royalc  and  Isabelle Bonnamoura  

* Corresponding authors

a Université de Lyon, Lyon, Université Lyon 1, Villeurbanne, CNRS, UMR5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, Laboratoire de Chimie Organique 2-CSAp, 43 Boulevard du 11 Novembre 1918, Villeurbanne, France
E-mail: ulrich.darbost@univ-lyon1.fr
Fax: +0334-72448438

b Université de Lyon, Université de Saint-Etienne, CNRS UMR 5516, Laboratoire Hubert Curien, Saint-Etienne, France

c Département de Chimie Moléculaire, Laboratoire de Chimie Inorganique Rédox, (DCM-CIRE-UMR CNRS/UJF 5250), Université Joseph Fourier, BP-53, 38041 Grenoble Cedex 9, France

Abstract

A new copper redox molecular switch based on a calixarene possessing both imidazole- and quinoline-like fragments displays, through an exchange of ligands triggered by an electrochemical input, unexpected long-lasting stability of both the redox forms, as well as fast reversible cycling.

Graphical abstract: A calixarene-based copper-centered redox switch as a data storage prototype

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Article information

DOI
https://doi.org/10.1039/B907207A
Article type
Communication
Submitted
08 Apr 2009
Accepted
14 Sep 2009
First published
28 Sep 2009

Chem. Commun., 2009, 6774-6776

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A calixarene-based copper-centered redox switch as a data storage prototype

U. Darbost, V. Penin, E. Jeanneau, C. Félix, F. Vocanson, C. Bucher, G. Royal and I. Bonnamour, Chem. Commun., 2009, 6774 DOI: 10.1039/B907207A

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