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Issue 21, 2009
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Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

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Abstract

Exceptional activity of [CuII(TPMA)Cl][Cl] (TPMA = tris(2-pyridylmethyl)amine) complex in atom transfer radical addition (ATRA) of CCl4 to 1,6-dienes followed by sequential atom transfer radical cyclization (ATRC) in the presence of free-radical diazo initiators as reducing agents is reported.

Graphical abstract: Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

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Article information


Submitted
24 Mar 2009
Accepted
18 Apr 2009
First published
05 May 2009

Chem. Commun., 2009, 3029-3031
Article type
Communication

Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

C. Ricardo and T. Pintauer, Chem. Commun., 2009, 3029
DOI: 10.1039/B905839G

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