Issue 23, 2009
From the journal:

Chemical Communications

Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation†

Fanny Bonnet,*a   Cristina Da Costa Violante,a   Pascal Roussel,a   André Mortreuxa  and  Marc Visseaux*a  

* Corresponding authors

a Synthèses Organométalliques et Catalyse, Unité de Catalyse et Chimie du Solide, UMR CNRS 8181, USTL-ENSCL, Cité Scientifique, Villeneuve d’Ascq, France
E-mail: fanny.bonnet@ensc-lille.fr, marc.visseaux@ensc-lille.fr
Fax: +33 3 20 43 65 85
Tel: +33 3 20 43 65 86

Abstract

Highly cis-1,4 polymerisation of isoprene and syndiospecific polymerisation of styrene were conducted using the same borohydrido half-sandwich scandium pre-initiator.

Graphical abstract: Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation

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Article information

DOI
https://doi.org/10.1039/B903403J
Article type
Communication
Submitted
17 Feb 2009
Accepted
21 Apr 2009
First published
14 May 2009

Chem. Commun., 2009, 3380-3382

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Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation

F. Bonnet, C. Da Costa Violante, P. Roussel, A. Mortreux and M. Visseaux, Chem. Commun., 2009, 3380 DOI: 10.1039/B903403J

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