Issue 23, 2009
From the journal:

Chemical Communications

Electrochemical structural transformation and reversible doping/dedoping of lithium phthalocyanine thin films

Maya Inagawa,a   Hirofumi Yoshikawa,a   Toshihiko Yokoyamab  and  Kunio Awaga*a  

* Corresponding authors

a Research Center for Materials Science & Department of Chemistry, Nagoya University, Furo-cho, Chikusa-ku, Nagoya Japan
E-mail: awaga@mbox.chem.nagoya-u.ac.jp
Fax: (+)81-52-789-2484
Tel: (+)81-52-789-2487

b Institute for Molecular Science, Okazaki Japan
E-mail: yokoyama@ims.ac.jp
Fax: (+)81-564-55-4639
Tel: (+)81-564-55-7345

Abstract

The α-form thin films (120 nm) of lithium phthalocyanine (LiPc) exhibit a structural transformation to the x-form by electrochemical oxidation which introduces the counter anions into the thin films, and these anions are reversibly dedoped by electrochemical re-reduction, maintaining the x-form structure.

Graphical abstract: Electrochemical structural transformation and reversible doping/dedoping of lithium phthalocyanine thin films

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Article information

DOI
https://doi.org/10.1039/B902903F
Article type
Communication
Submitted
11 Feb 2009
Accepted
26 Mar 2009
First published
24 Apr 2009

Chem. Commun., 2009, 3389-3391

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Electrochemical structural transformation and reversible doping/dedoping of lithium phthalocyanine thin films

M. Inagawa, H. Yoshikawa, T. Yokoyama and K. Awaga, Chem. Commun., 2009, 3389 DOI: 10.1039/B902903F

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