Issue 19, 2009
From the journal:

Chemical Communications

Heterometallic 3d–4f cubane clusters inserted in polyoxometalate matrices†

Brigitte Nohra,a   Pierre Mialane,*a   Anne Dolbecq,a   Eric Rivière,b   Jérôme Marrota  and  Francis Sécheressea  

* Corresponding authors

a Institut Lavoisier de Versailles, UMR 8180, Université de Versailles Saint-Quentin, 45 avenue des Etats-Unis, Versailles Cedex, France
E-mail: mialane@chimie.uvsq.fr

b Institut de Chimie Moléculaire et des Matériaux d’Orsay, UMR 8182, Equipe Chimie Inorganique, Univ. Paris-Sud 11, 91405 Orsay Cedex, France

Abstract

Unprecedented molecular and bidimensional compounds based on monovacant polyoxometalates capped by heterometallic 3d–4f {LnCu3(OH)3O} (Ln = La, Gd, Eu) cubane fragments have been characterized and their magnetic properties investigated.

Graphical abstract: Heterometallic 3d–4f cubane clusters inserted in polyoxometalate matrices

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Article information

DOI
https://doi.org/10.1039/B902094B
Article type
Communication
Submitted
02 Feb 2009
Accepted
03 Mar 2009
First published
27 Mar 2009

Chem. Commun., 2009, 2703-2705

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Heterometallic 3d–4f cubane clusters inserted in polyoxometalate matrices

B. Nohra, P. Mialane, A. Dolbecq, E. Rivière, J. Marrot and F. Sécheresse, Chem. Commun., 2009, 2703 DOI: 10.1039/B902094B

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