Issue 19, 2009
From the journal:

Chemical Communications

Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes†

Javier Ruiz*a  and  Bernabé F. Perandonesa  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Oviedo, Spain
E-mail: jruiz@uniovi.es
Fax: +34985103446
Tel: +34985102977

Abstract

Oxazole and thiazole molecules N-coordinated to manganese(I) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid–base reactions, and subsequently transmetalated to gold(I), via isolable heterometallic intermediates.

Graphical abstract: Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/B900955H
Article type
Communication
Submitted
16 Jan 2009
Accepted
27 Feb 2009
First published
23 Mar 2009

Chem. Commun., 2009, 2741-2743

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Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes

J. Ruiz and B. F. Perandones, Chem. Commun., 2009, 2741 DOI: 10.1039/B900955H

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