Issue 10, 2009
From the journal:

Chemical Communications

Diffusion NMR and trilinear analysis in the study of reaction kinetics

Mathias Nilsson,*a   Maryam Khajeh,a   Adolfo Botana,a   Michael A. Bernsteinb  and  Gareth A. Morrisa  

* Corresponding authors

a School of Chemistry, University of Manchester, Oxford Road, Manchester, UK

b AstraZeneca R&D Charnwood, Bakewell Rd, Loughborough, Leics, UK
E-mail: mathias.nilsson@manchester.ac.uk

Abstract

Measurement of diffusion-weighted NMR spectra as a function of time allows the time-dependence of concentration and the isolated spectrum to be found for each component in a reaction, without prior assumptions about spectra, kinetics or diffusion behaviour, by data decomposition using the PARAFAC algorithm.

Graphical abstract: Diffusion NMR and trilinear analysis in the study of reaction kinetics

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Article information

DOI
https://doi.org/10.1039/B820813A
Article type
Communication
Submitted
20 Nov 2008
Accepted
10 Dec 2008
First published
15 Jan 2009

Chem. Commun., 2009, 1252-1254

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Diffusion NMR and trilinear analysis in the study of reaction kinetics

M. Nilsson, M. Khajeh, A. Botana, M. A. Bernstein and G. A. Morris, Chem. Commun., 2009, 1252 DOI: 10.1039/B820813A

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