Issue 16, 2009
From the journal:

Chemical Communications

Saddle-shaped six-coordinate iron(iii) porphyrin complex with unusual intermediate-spin electronic structure†

Ru-Jen Cheng,*a   Chia-Wei Chao,a   Ya-Ping Han,a   Yen-Chou Chena  and  Chiao-Han Tinga  

* Corresponding authors

a Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan, Republic of China
E-mail: rjcheng@mail.nchu.edu.tw
Fax: 886-4-22862547
Tel: 886-4-22871190

Abstract

An unusual intermediate-spin electronic structure dxz,yz3dxy1dz21 has been assigned to the six-coordinate saddled [Fe(OETPP)(4-CNPy)2]+ complex through density functional calculation and NMR spectroscopy analysis.

Graphical abstract: Saddle-shaped six-coordinate iron(iii) porphyrin complex with unusual intermediate-spin electronic structure

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B820443H
Article type
Communication
Submitted
17 Nov 2008
Accepted
09 Feb 2009
First published
27 Feb 2009

Chem. Commun., 2009, 2180-2182

Permissions

Request permissions

Saddle-shaped six-coordinate iron(III) porphyrin complex with unusual intermediate-spin electronic structure

R. Cheng, C. Chao, Y. Han, Y. Chen and C. Ting, Chem. Commun., 2009, 2180 DOI: 10.1039/B820443H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements