Issue 9, 2009
From the journal:

Chemical Communications

Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin†

Sumito Tokuji,a   Yuji Takahashi,b   Hideyuki Shinmori,*b   Hiroshi Shinokubo*a  and  Atsuhiro Osuka*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Japan
E-mail: osuka@kuchem.kyoto-u.ac.jp, hshino@apchem.nagoya-u.ac.jp
Fax: +81 75-753-3970
Tel: +81 75-753-4008

b Division of Medicine and Engineering Science, Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi, 4-3-11 Takeda, Japan
E-mail: shinmori@yamanashi.ac.jp
Tel: +81 55-220-8566

Abstract

The treatment of 3,5-dibenzoylporphyrins with ammonium acetate provided novel oxopyridochlorins as the first examples of pyridine-fused porphyrinoids, which displayed absorption bands reaching into the near IR region and an ability to sensitize singlet oxygen effectively.

Graphical abstract: Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin

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Article information

DOI
https://doi.org/10.1039/B819284G
Article type
Communication
Submitted
30 Oct 2008
Accepted
28 Nov 2008
First published
06 Jan 2009

Chem. Commun., 2009, 1028-1030

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Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin

S. Tokuji, Y. Takahashi, H. Shinmori, H. Shinokubo and A. Osuka, Chem. Commun., 2009, 1028 DOI: 10.1039/B819284G

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