Issue 6, 2009
From the journal:

Chemical Communications

A tris(alkyl)yttrium compound containing six β-agostic Si–H interactions†

KaKing Yan,a   Andrew V. Pawlikowski,a   Chris Eberta  and  Aaron D. Sadow*a  

* Corresponding authors

a Iowa State University and Ames Laboratory, Ames, IA, USA
E-mail: sadow@iastate.edu
Fax: +1 (0)515294 0105
Tel: +1 (0)515 294 8069

Abstract

The new homoleptic rare earth compound [Y(C(SiHMe2)3)3] (2) is prepared in 82% yield by salt metathesis of YCl3 and 3 equivalents of [KC(SiHMe2)3] (1); two β-agostic Y⋯(H–Si) interactions are observed for each C(SiHMe2)3 ligand in 2, giving six agostic interactions per yttrium(III) center.

Graphical abstract: A tris(alkyl)yttrium compound containing six β-agostic Si–H interactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B818630H
Article type
Communication
Submitted
22 Oct 2008
Accepted
20 Nov 2008
First published
12 Dec 2008

Chem. Commun., 2009, 656-658

Permissions

Request permissions

A tris(alkyl)yttrium compound containing six β-agostic Si–H interactions

K. Yan, A. V. Pawlikowski, C. Ebert and A. D. Sadow, Chem. Commun., 2009, 656 DOI: 10.1039/B818630H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements