Unsuspected mesomorphism in “tail-free” cyclopalladated 3,5-disubstituted-2-(2′-pyridyl)pyrroles†
Abstract
The first cyclopalladation of 3,5-disubstituted-2-(2′-pyridyl)pyrroles leads to columnar metallomesogens of non-conventional molecular shape.
* Corresponding authors
a
Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM Unità INSTM della Calabria and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030 Arcavacata di Rende CS, Italy
E-mail:
d.pucci@unical.it
Fax: +39 0984 492066
Tel: +39 0984 492064
The first cyclopalladation of 3,5-disubstituted-2-(2′-pyridyl)pyrroles leads to columnar metallomesogens of non-conventional molecular shape.
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D. Pucci, I. Aiello, A. Aprea, A. Bellusci, A. Crispini and M. Ghedini, Chem. Commun., 2009, 1550 DOI: 10.1039/B818603K
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