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A discrete S6-symmetrical (H2O)32cluster was encapsulated in the cavity of an organic co-crystalline supermolecule constructed by the co-crystallization of guanidinium and benzenetribenzoate ions through hydrogen bonds, π–π and cation–π interactions.

Graphical abstract: Molecular encapsulation of a discrete (H2O)32cluster with S6 symmetry in an organic crystalline supermolecule

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