Issue 9, 2009
From the journal:

Analyst

Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid–liquid interfaces

Daniel M. Meier,a   Atsushi Urakawa*a  and  Alfons Baiker*a  

* Corresponding authors

a Department of Chemistry and Applied Biosciences, ETH Zurich, Hönggerberg, CH-8093 Zurich, Switzerland
E-mail: baiker@chem.ethz.ch, urakawa@chem.ethz.ch
Fax: +41 44 632 11 63
Tel: +41 44 632 31 53

Abstract

Polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS) combined with concentration modulation allows simultaneous monitoring of dynamic evolutions of surface and liquid phase species during reactions at catalytic interfaces as demonstrated for the Pt-catalysed oxidation of CO by O2 in cyclohexane.

Graphical abstract: Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid–liquid interfaces

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Article information

DOI
https://doi.org/10.1039/B911151D
Article type
Communication
Submitted
08 Jun 2009
Accepted
20 Jul 2009
First published
27 Jul 2009

Analyst, 2009,134, 1779-1780

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Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid–liquid interfaces

D. M. Meier, A. Urakawa and A. Baiker, Analyst, 2009, 134, 1779 DOI: 10.1039/B911151D

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