Issue 12, 2008
From the journal:

Photochemical & Photobiological Sciences

Kinetics of geminate recombination of organic free radicals in viscous solvents†

Igor Khudyakov,*a   Peter Levinb  and  Vladimir Kuzminb  

* Corresponding authors

a Bomar Specialties, Torrington, CT, USA
E-mail: ikhudyakov@bomarspecialties.com

b N.M. Emanuel Institute for Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

Abstract

The kinetics of geminate recombination of multiatomic organic free radicals in glycerol solutions have been investigated. Radicals were produced by ns laser flash photolysis under photoreduction of carbonyl compounds. An external moderate magnetic field decelerates geminate recombination leading to smaller cage effect values. The duration of geminate recombination is discussed.

Graphical abstract: Kinetics of geminate recombination of organic free radicals in viscous solvents

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Article information

DOI
https://doi.org/10.1039/B810884F
Article type
Paper
Submitted
26 Jun 2008
Accepted
29 Aug 2008
First published
15 Sep 2008

Photochem. Photobiol. Sci., 2008,7, 1540-1543

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Kinetics of geminate recombination of organic free radicals in viscous solvents

I. Khudyakov, P. Levin and V. Kuzmin, Photochem. Photobiol. Sci., 2008, 7, 1540 DOI: 10.1039/B810884F

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