Issue 5, 2008
From the journal:

Photochemical & Photobiological Sciences

Vibrational deactivation of singlet oxygen: does it play a role in stereoselectivity during photooxygenation?†‡

Marissa Solomon,a   J. Sivaguru,*b   Steffen Jockusch,a   Waldemar Adam*cd  and  Nicholas J. Turro*ae  

* Corresponding authors

a The Department of Chemistry, Columbia University, New York, NY, USA

b Department of Chemistry and Molecular Biology, North Dakota State University, Fargo, ND, USA
E-mail: sivaguru.jayaraman@ndsu.edu

c Institute für Organische Chemie, Universität Würzburg, Würzburg, Germany
E-mail: wadam@chemie.uni-wuerzburg.de

d The Department of Chemistry, University of Puerto Rico, Facundo Bueso 110, Rio Piedras, PR, USA

e The Department of Chemical Engineering, Columbia University, New York, NY, USA
E-mail: njt3@columbia.edu

Abstract

Oxazolidinone-substituted enecarbamates offer a system to explore vibrational quenching and the strategic placement of CH bonds as a method for manipulating the stereoselectivity of photoreactions.

Graphical abstract: Vibrational deactivation of singlet oxygen: does it play a role in stereoselectivity during photooxygenation?

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Article information

DOI
https://doi.org/10.1039/B719387D
Article type
Communication
Submitted
17 Dec 2007
Accepted
28 Feb 2008
First published
13 Mar 2008

Photochem. Photobiol. Sci., 2008,7, 531-533

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Vibrational deactivation of singlet oxygen: does it play a role in stereoselectivity during photooxygenation?

M. Solomon, J. Sivaguru, S. Jockusch, W. Adam and N. J. Turro, Photochem. Photobiol. Sci., 2008, 7, 531 DOI: 10.1039/B719387D

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