Photocatalysis by tetraphenylporphyrin of the decomposition of chloroform

Abstract

Irradiation of solutions of tetraphenylporphyrin (H₂TPP) in chloroform causes decomposition of the chloroform at UV wavelengths higher than those that decompose chloroform directly. The catalytic cycle involves photooxidation of the porphyrin followed by thermal reduction. Photocatalysis continues after H₂TPP has been completely protonated by the HCl produced during decomposition, and the rate of HCl production accelerates as a second pathway, in which CCl₃OOH oxidizes the porphyrin, becomes important.