Issue 15, 2008
From the journal:

Organic & Biomolecular Chemistry

A new type of self-supported, polymeric Ru-carbene complex for homogeneous catalysis and heterogeneous recovery: synthesis and catalytic activities for ring-closing metathesis†

Shu-Wei Chen,a   Ju Hyun Kim,a   Hyunik Shinb  and  Sang-gi Lee*a  

* Corresponding authors

a Department of Chemistry and Nano Science (BK21), Ewha Womans University, Seoul, Korea
E-mail: sanggi@ewha.ac.kr
Fax: +82-2-3277-3419
Tel: +82-2-3277-4505

b Chemical Development Division, LG Life Sciences, Ltd./R&D, Daejeon, Korea

Abstract

A novel 2nd generation Grubbs-type catalyst tethering an isopropoxystyrene has been synthesized and automatically polymerized in solution to form a self-supported polymeric Ru-carbene complex, which catalyzed ring-closing metathesis homogeneously, but was recovered heterogeneously.

Graphical abstract: A new type of self-supported, polymeric Ru-carbene complex for homogeneous catalysis and heterogeneous recovery: synthesis and catalytic activities for ring-closing metathesis

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Article information

DOI
https://doi.org/10.1039/B809025D
Article type
Communication
Submitted
28 May 2008
Accepted
17 Jun 2008
First published
30 Jun 2008

Org. Biomol. Chem., 2008,6, 2676-2678

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A new type of self-supported, polymeric Ru-carbene complex for homogeneous catalysis and heterogeneous recovery: synthesis and catalytic activities for ring-closing metathesis

S. Chen, J. H. Kim, H. Shin and S. Lee, Org. Biomol. Chem., 2008, 6, 2676 DOI: 10.1039/B809025D

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