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Issue 4, 2008
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Polycyclic framework synthesis of anominine and tubingensin Aindole diterpenoids

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Abstract

A highly congested decalin embodying an α-methylene ketone is synthesized in 11 steps from the Wieland–Miescher ketone and efficiently converted to the polycyclic frameworks of anominine and tubingensin A, which constitutes the first approach to the skeleton of these indole diterpenoids.

Graphical abstract: Polycyclic framework synthesis of anominine and tubingensin A indole diterpenoids

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Article information


Submitted
27 Nov 2007
Accepted
18 Dec 2007
First published
17 Jan 2008

Org. Biomol. Chem., 2008,6, 772-778
Article type
Paper

Polycyclic framework synthesis of anominine and tubingensin A indole diterpenoids

B. Bradshaw, G. Etxebarria-Jardí and J. Bonjoch, Org. Biomol. Chem., 2008, 6, 772
DOI: 10.1039/B718280E

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