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Issue 4, 2008
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Polycyclic framework synthesis of anominine and tubingensin A indole diterpenoids

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Abstract

A highly congested decalin embodying an α-methylene ketone is synthesized in 11 steps from the Wieland–Miescher ketone and efficiently converted to the polycyclic frameworks of anominine and tubingensin A, which constitutes the first approach to the skeleton of these indole diterpenoids.

Graphical abstract: Polycyclic framework synthesis of anominine and tubingensin A indole diterpenoids

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Publication details

The article was received on 27 Nov 2007, accepted on 18 Dec 2007 and first published on 17 Jan 2008


Article type: Paper
DOI: 10.1039/B718280E
Org. Biomol. Chem., 2008,6, 772-778

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    Polycyclic framework synthesis of anominine and tubingensin A indole diterpenoids

    B. Bradshaw, G. Etxebarria-Jardí and J. Bonjoch, Org. Biomol. Chem., 2008, 6, 772
    DOI: 10.1039/B718280E

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