Issue 2, 2008
From the journal:

Organic & Biomolecular Chemistry

Diels–Alder approach to biaryls (DAB): Importance of the ortho-nitro moiety in the [4 + 2] cycloaddition†

Bradley O. Ashburna  and  Rich G. Carter*a  

* Corresponding authors

a Department of Chemistry, 153 Gilbert Hall, Oregon State University, Corvallis, OR, USA
E-mail: rich.carter@oregonstate.edu
Fax: +1 (541) 737-9496
Tel: +1 (541) 737-9486

Abstract

A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition–cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target biaryls in superior yields as compared to the meta and paranitro substituted variants.

Graphical abstract: Diels–Alder approach to biaryls (DAB): Importance of the ortho-nitro moiety in the [4 + 2] cycloaddition

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B714893C
Article type
Communication
Submitted
27 Sep 2007
Accepted
16 Nov 2007
First published
27 Nov 2007

Org. Biomol. Chem., 2008,6, 255-257

Permissions

Request permissions

Diels–Alder approach to biaryls (DAB): Importance of the ortho-nitro moiety in the [4 + 2] cycloaddition

B. O. Ashburn and R. G. Carter, Org. Biomol. Chem., 2008, 6, 255 DOI: 10.1039/B714893C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements