Issue 2, 2008
From the journal:

New Journal of Chemistry

Exo-coordinated discrete and continuous supramolecular silver(i) complexes with thiaoxa-macrocycles†

Hyun Jee Kim,a   Il Yoon,a   So Young Lee,a   Kyu Seong Choib  and  Shim Sung Lee*a  

* Corresponding authors

a Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University, S. Korea
E-mail: sslee@gnu.ac.kr
Fax: +8255 7537614
Tel: +8255 751 6021

b Department of Chemistry, Kyungnam University, S. Korea

Abstract

Two thiaoxa-macrocycles (L1: S3O2 and L2: S2O3) with a dibenzo-subunit were synthesised and structurally characterised by X-ray analysis. Reactions of L1 and L2 with silver(I) salts (NO3− and PF6−) afforded the respective ligand- and/or anion-directed complexes 1–3 with different topologies; tetranuclear sandwich [Ag4(L1)2(NO3)4] (1), cyclic tetramer [Ag4(L1)4](PF6)4 (2) and poly(bicyclic dimer) [Ag(L2)NO3]n (3). The formation of such supramolecular complexes is discussed in terms of donor or anion effect.

Graphical abstract: Exo-coordinated discrete and continuous supramolecular silver(i) complexes with thiaoxa-macrocycles

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Article information

DOI
https://doi.org/10.1039/B710581A
Article type
Paper
Submitted
10 Jul 2007
Accepted
26 Sep 2007
First published
09 Oct 2007

New J. Chem., 2008,32, 258-263

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Exo-coordinated discrete and continuous supramolecular silver(I) complexes with thiaoxa-macrocycles

H. J. Kim, I. Yoon, S. Y. Lee, K. S. Choi and S. S. Lee, New J. Chem., 2008, 32, 258 DOI: 10.1039/B710581A

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