Issue 2, 2008
From the journal:

Green Chemistry

Stereochemical effects on the mode of facilitated ion transfer into room-temperature ionic liquids

Mark L. Dietz,*a   Sandrine Jakab,ab   Kazuhiro Yamatoc  and  Richard A. Bartschc  

* Corresponding authors

a Argonne National Laboratory, Chemistry Division, Bldg. 200, 9700 S. Cass Avenue, Argonne, IL, USA
E-mail: mdietz@anl.gov
Fax: +1-630-252-7501
Tel: +1-630-252-3647

b Ecole Nationale Superieure de Chimie de Paris, Paris, France

c Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX, USA

Abstract

Crown ether stereochemistry is shown to influence the mode of sodium ion partitioning between acidic nitrate media and a dialkylimidazolium-based room temperature ionic liquid containing various dicyclohexano-18-crown-6 (DCH18C6) isomers, in contrast to an analogous extraction system employing a conventional organic solvent.

Graphical abstract: Stereochemical effects on the mode of facilitated ion transfer into room-temperature ionic liquids

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Article information

DOI
https://doi.org/10.1039/B713750H
Article type
Communication
Submitted
07 Sep 2007
Accepted
22 Nov 2007
First published
05 Dec 2007

Green Chem., 2008,10, 174-176

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Stereochemical effects on the mode of facilitated ion transfer into room-temperature ionic liquids

M. L. Dietz, S. Jakab, K. Yamato and R. A. Bartsch, Green Chem., 2008, 10, 174 DOI: 10.1039/B713750H

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