Issue 2, 2008
From the journal:

Green Chemistry

Recent advances in C–H bond formation in aqueous media: a mechanistic perspective

V. Tamara Perchyonok,*ab   Ioannis N. Lykakis*c  and  Kellie L. Tuck*b  

* Corresponding authors

a Centre for Green Chemistry, Monash University, Clayton, Australia

b School of Chemistry, Monash University, Clayton, Australia
E-mail: tamara.perchyonok@sci.monash.edu.au, kellie.tuck@sci.monash.edu.au

c Department of Chemistry, University of Crete, Iraklion, Voutes, Crete, Greece
E-mail: lykakis@chemistry.uoc.gr

Abstract

Recent advances in free-radical chemistry have expanded the versatility and flexibility of carbon–hydrogen bond formation in aqueous media. This review highlights progress made in the last decade to “tame” reactive free-radical species in aqueous-phase reactions. Detailed are a broad range of synthetically useful transformations and their application in synthesis, DNA structural probing and isotope labelling. The review provides some practical hints useful for the design of high-yielding free-radical reactions in aqueous media.

Graphical abstract: Recent advances in C–H bond formation in aqueous media: a mechanistic perspective

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Article information

DOI
https://doi.org/10.1039/B709047A
Article type
Tutorial Review
Submitted
15 Jun 2007
Accepted
09 Nov 2007
First published
22 Nov 2007

Green Chem., 2008,10, 153-163

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Recent advances in C–H bond formation in aqueous media: a mechanistic perspective

V. T. Perchyonok, I. N. Lykakis and K. L. Tuck, Green Chem., 2008, 10, 153 DOI: 10.1039/B709047A

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