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Issue 43, 2008
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Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

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Abstract

Cyclic diamino plumbylenes derived from saturated heterocycles are obtained from deprotonation of diamines and subsequent reaction with PbCl2, or by reaction of a suitable diamine with Pb[N(SiMe3)2]2. Single crystal X-ray studies have been used to probe the solid state structures of a range of these complexes and have shown the fine balance between monomer and dimer formation which is related to the bulk of the organic group attached to the nitrogen atoms. Dimerisation is also shown to effect structural changes within the core of the heterocyclic plumbylene.

Graphical abstract: Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

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Publication details

The article was received on 22 May 2008, accepted on 22 Jul 2008 and first published on 23 Sep 2008


Article type: Paper
DOI: 10.1039/B808717B
Citation: Dalton Trans., 2008,0, 6055-6059

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    Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

    J. P. H. Charmant, M. F. Haddow, F. E. Hahn, D. Heitmann, R. Fröhlich, S. M. Mansell, C. A. Russell and D. F. Wass, Dalton Trans., 2008, 0, 6055
    DOI: 10.1039/B808717B

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