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Issue 24, 2008
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Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

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Abstract

The effect of acetate concentration on the formation of {SiW10Fe2}-based complexes is demonstrated by the synthesis of an open-shell diiron tungstosilicate derivative featuring two rotational Keggin isomer units.

Graphical abstract: Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

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Publication details

The article was received on 06 Feb 2008, accepted on 21 Apr 2008 and first published on 07 May 2008


Article type: Communication
DOI: 10.1039/B802147C
Citation: Dalton Trans., 2008,0, 3150-3152

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    Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

    B. Botar and P. Kögerler, Dalton Trans., 2008, 0, 3150
    DOI: 10.1039/B802147C

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