A sheet of clusters: self-assembly of a (4,4) network of FeIII10clusters

David R. Turner; Sze Nee Pek; John D. Cashion; Boujemaa Moubaraki; Keith S. Murray; Stuart R. Batten

doi:10.1039/B815084B

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A sheet of clusters: self-assembly of a (4,4) network of Fe^III₁₀clusters†

David R. Turner,^a Sze Nee Pek,^a John D. Cashion,^b Boujemaa Moubaraki,^a Keith S. Murray^a and Stuart R. Batten*^a

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* Corresponding authors

^a School of Chemistry, Monash University, Clayton, Victoria, Australia
E-mail: stuart.batten@sci.monash.edu.au
Fax: +61 (0)3 9905 4597
Tel: +61 (0)3 9905 4606

^b School of Physics, Monash University, Clayton, Victoria, Australia

Abstract

A 2D sheet of Fe^III₁₀clusters has been synthesised in which the antiferromagnetic clusters act as 4-connecting nodes using ligands that both chelate and bridge between Fe atoms supported by diagonal hydrogen bonding.

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Article information

DOI: https://doi.org/10.1039/B815084B
Article type: Communication
Submitted: 29 Aug 2008
Accepted: 20 Oct 2008
First published: 28 Oct 2008

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Dalton Trans., 2008, 6877-6879

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A sheet of clusters: self-assembly of a (4,4) network of Fe^III₁₀clusters

D. R. Turner, S. N. Pek, J. D. Cashion, B. Moubaraki, K. S. Murray and S. R. Batten, Dalton Trans., 2008, 6877 DOI: 10.1039/B815084B

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Dalton Transactions