Issue 36, 2008
From the journal:

Dalton Transactions

Formation and X-ray structure of a seven-membered C4OBN heterocycle by a THF ring-expansion process†

Andrea M. Correntea  and  Tristram Chivers*a  

* Corresponding authors

a Department of Chemistry, University of Calgary, Calgary, Alberta, Canada
E-mail: chivers@ucalgary.ca
Fax: +1 (403) 289-9488
Tel: +1 (403) 220-5741

Abstract

The reaction of BCl3 with two equivalents of LiN(H)Dipp (Dipp = 2,6-diisopropylphenyl) in THF produces DippN(H)BO(CH2)4NDipp, which contains a puckered seven-membered C4OBN ring.

Graphical abstract: Formation and X-ray structure of a seven-membered C4OBN heterocycle by a THF ring-expansion process

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Article information

DOI
https://doi.org/10.1039/B810319D
Article type
Communication
Submitted
18 Jun 2008
Accepted
11 Jul 2008
First published
29 Jul 2008

Dalton Trans., 2008, 4840-4842

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Formation and X-ray structure of a seven-membered C4OBN heterocycle by a THF ring-expansion process

A. M. Corrente and T. Chivers, Dalton Trans., 2008, 4840 DOI: 10.1039/B810319D

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