Syntheses, structures and properties of seven isomorphous 1D Ln3+complexes Ln(BTA)(HCOO)(H2O)3 (H2BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr, Nd)

Abstract

Seven isomorphous 1D chain Ln³⁺ complexes Ln(BTA)(HCOO)(H₂O)₃ (Ln = Pr (1), Gd (2), Eu (3), Tb (4) Dy (5), Er (6) and Yb (7)), and two formate coordinating and bridging 3D Ln³⁺ complexes Ln(HCOO)₃ (Ln = Pr (8) and Nd (9)) have been synthesized and characterized by single crystal X-ray diffraction analysis. Although the Ln³⁺ ions in 1–7 have different radius, the trivalent lanthanide ions in 1–7 show the same coordinated environment. The well-defined single crystal structures of 8 and 9 are first samples for formate-bridged Ln³⁺ metallic complexes. The luminescent properties of solid samples of 2–5 at room temperature and the magnetic property of 2 have been also reported and discussed in this paper.