Issue 31, 2008
From the journal:

Dalton Transactions

A unique six-membered chelated iridium complex†

Sven Ammermann,a   Constantin Daniliuc,b   Peter G. Jones,b   Wolf-Walther du Mont,b   Wolfgang Kowalskya  and  Hans-Hermann Johannes*a  

* Corresponding authors

a Labor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Postfach 3329, Braunschweig, Germany
E-mail: h2.johannes@ihf.tu-bs.de
Fax: +49-531-391-2006
Tel: +49-531-391-8004

b Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, Braunschweig, Germany

Abstract

The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl3·nH2O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.

Graphical abstract: A unique six-membered chelated iridium complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B807735P
Article type
Communication
Submitted
06 May 2008
Accepted
06 Jun 2008
First published
16 Jun 2008

Dalton Trans., 2008, 4095-4098

Permissions

Request permissions

A unique six-membered chelated iridium complex

S. Ammermann, C. Daniliuc, P. G. Jones, W. du Mont, W. Kowalsky and H. Johannes, Dalton Trans., 2008, 4095 DOI: 10.1039/B807735P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements