Charge separation by ditopic complexation in the solid state: molecular structure of {Ph2(I)SnCH2Sn(Ph)(I)CH2-[16]-crown-5}·NaF·CH3OH

Gregor Reeske; Markus Schürmann; Klaus Jurkschat

doi:10.1039/B803552K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Charge separation by ditopic complexation in the solid state: molecular structure of {Ph₂(I)SnCH₂Sn(Ph)(I)CH₂-[16]-crown-5}·NaF·CH₃OH†

Gregor Reeske,^a Markus Schürmann^a and Klaus Jurkschat*^a

Author affiliations

* Corresponding authors

^a Lehrstuhl für Anorganische Chemie II, Technische Universität Dortmund, 44221 Dortmund
E-mail: klaus.jurkschat@uni-dortmund.de
Fax: +49(0)231-5048

Abstract

An intramolecular O–H⋯F hydrogen bridge involving a methanol molecule provides communication between the strongly separated sodium cation and fluoride anion in sodium fluoride that is, for the first time and despite its high lattice energy, ditopically complexed by an organotin-substituted crown ether.

This article is part of the themed collection: Main group chemistry: from molecules to materials

Download options Please wait...

Supplementary files

Crystal structure data TXT (32K)

Article information

DOI: https://doi.org/10.1039/B803552K
Article type: Communication
Submitted: 29 Feb 2008
Accepted: 03 Mar 2008
First published: 18 Mar 2008

Download Citation

Dalton Trans., 2008, 3398-3400

Permissions

Request permissions

Charge separation by ditopic complexation in the solid state: molecular structure of {Ph₂(I)SnCH₂Sn(Ph)(I)CH₂-[16]-crown-5}·NaF·CH₃OH

G. Reeske, M. Schürmann and K. Jurkschat, Dalton Trans., 2008, 3398 DOI: 10.1039/B803552K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions