Issue 14, 2008
From the journal:

Dalton Transactions

High-valent iron-mediated cis-hydroxyacetoxylation of olefins

Ruben Mas-Balleste,a   Megumi Fujitaa  and  Lawrence Que, Jr.*a  

* Corresponding authors

a Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN, USA
E-mail: larryque@umn.edu
Fax: +1-612-624-7029
Tel: +1-612-625-0389

Abstract

Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H2O2 that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)FeV(O)(OAc)]2+ oxidant.

Graphical abstract: High-valent iron-mediated cis-hydroxyacetoxylation of olefins

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Article information

DOI
https://doi.org/10.1039/B802587H
Article type
Communication
Submitted
14 Feb 2008
Accepted
18 Feb 2008
First published
04 Mar 2008

Dalton Trans., 2008, 1828-1830

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High-valent iron-mediated cis-hydroxyacetoxylation of olefins

R. Mas-Balleste, M. Fujita and L. Que, Jr., Dalton Trans., 2008, 1828 DOI: 10.1039/B802587H

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