Issue 33, 2008

Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes

Abstract

The complexes [Ni{(SePiPr2)2N}2] (1), [Ni(Se2PiPr2)2] (2), and [Co(Se2PiPr2)2] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(II) (1), -cobalt(II) [Co{(SePiPr2)2N}2] (3), diselenophosphinato-nickel(II) (2), -cobalt(II) (4) and diselenocarbamato-nickel(II) [Ni(Se2CNEt2)2] (5), and -cobalt(III) [Co(Se2CNEt2)3] (6) precursors.

Graphical abstract: Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes

Supplementary files

Article information

Article type
Paper
Submitted
06 Feb 2008
Accepted
03 Apr 2008
First published
23 Jul 2008

Dalton Trans., 2008, 4499-4506

Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes

A. Panneerselvam, C. Q. Nguyen, J. Waters, M. A. Malik, P. O'Brien, J. Raftery and M. Helliwell, Dalton Trans., 2008, 4499 DOI: 10.1039/B802012D

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