Issue 33, 2008
From the journal:

Dalton Transactions

Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes†‡

Arunkumar Panneerselvam,a   Chinh Q. Nguyen,a   John Waters,a   Mohammad A. Malik,a   Paul O'Brien,*a   James Rafteryb  and  Madeleine Helliwellb  

* Corresponding authors

a The School of Chemistry and The School of Materials, The University of Manchester, Oxford Road, Manchester, UK
E-mail: paul.obrien@manchester.ac.uk, azad.malik@manchester.ac.uk
Fax: +44 (0)161 275 4598
Tel: +44 (0)161 275 4652

b The School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

Abstract

The complexes [Ni{(SePiPr2)2N}2] (1), [Ni(Se2PiPr2)2] (2), and [Co(Se2PiPr2)2] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(II) (1), -cobalt(II) [Co{(SePiPr2)2N}2] (3), diselenophosphinato-nickel(II) (2), -cobalt(II) (4) and diselenocarbamato-nickel(II) [Ni(Se2CNEt2)2] (5), and -cobalt(III) [Co(Se2CNEt2)3] (6) precursors.

Graphical abstract: Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes

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Article information

DOI
https://doi.org/10.1039/B802012D
Article type
Paper
Submitted
06 Feb 2008
Accepted
03 Apr 2008
First published
23 Jul 2008

Dalton Trans., 2008, 4499-4506

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Ligand influence on the formation of P/Se semiconductor materials from metal–organic complexes

A. Panneerselvam, C. Q. Nguyen, J. Waters, M. A. Malik, P. O'Brien, J. Raftery and M. Helliwell, Dalton Trans., 2008, 4499 DOI: 10.1039/B802012D

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