Issue 17, 2008
From the journal:

Dalton Transactions

Synthesis and characterization of the first metallacyclooctane†

Akella Sivaramakrishna,a   Hong Sua  and  John R. Moss*a  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Cape Town, Rondebosch 7701, South Africa
E-mail: John.Moss@uct.ac.za
Fax: +27 21 689-7499
Tel: +27 21 650-2535

Abstract

Ring closing metathesis (RCM) using Grubbs’ 1st generation catalyst with cis-[L2Pt(CH2CH2CH[double bond, length as m-dash]CH2)(CH2CH2CH2CH[double bond, length as m-dash]CH2)] yields a platinacyclooctene which can be hydrogenated to the platinacyclooctane, L2Pt(CH2)7 [L2 = Ph2PCH2CH2CH2PPh2 (dppp) or Ph2PCH2CH2PPh2 (dppe)] in high yield.

Graphical abstract: Synthesis and characterization of the first metallacyclooctane

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Article information

DOI
https://doi.org/10.1039/B800843B
Article type
Communication
Submitted
16 Jan 2008
Accepted
25 Jan 2008
First published
19 Feb 2008

Dalton Trans., 2008, 2228-2231

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Synthesis and characterization of the first metallacyclooctane

A. Sivaramakrishna, H. Su and J. R. Moss, Dalton Trans., 2008, 2228 DOI: 10.1039/B800843B

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