Issue 14, 2008
From the journal:

Dalton Transactions

Electron density controlled carbamate ligand binding mode: towards a better understanding of metalloenzyme activity†

C. Neuhäuser,a   D. Domide,a   J. Mautz,a   E. Kaifera  and  H.-J. Himmel*a  

* Corresponding authors

a Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg, Germany
E-mail: hans-jorg.himmel@aci.uni-heidelberg.de
Fax: +49 6221 54 5707
Tel: +49 6221 54 8446

Abstract

The first structurally characterized mononuclear biscarbamate complex of Zn with η1-coordinated carbamate ligands can be prepared by reaction between [EtZn(O2CN(iBu)2)]4 and a guanidine base. Usage of a weaker base leads to η2-coordinated complexes.

Graphical abstract: Electron density controlled carbamate ligand binding mode: towards a better understanding of metalloenzyme activity

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Article information

DOI
https://doi.org/10.1039/B800687N
Article type
Communication
Submitted
14 Jan 2008
Accepted
24 Jan 2008
First published
18 Feb 2008

Dalton Trans., 2008, 1821-1824

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Electron density controlled carbamate ligand binding mode: towards a better understanding of metalloenzyme activity

C. Neuhäuser, D. Domide, J. Mautz, E. Kaifer and H.-J. Himmel, Dalton Trans., 2008, 1821 DOI: 10.1039/B800687N

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