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Issue 33, 2008
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1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker

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Abstract

The presence of a second 1,3-diborata-2,4-diphosphoniocyclobutane-1,3-diyl in the para-position of a phenylene linker favors the diradical form over the 1,3-diborata-2,4-diphosphoniobicyclo[1.1.0]butane bond stretch isomer, as long as the two planar diradical units are coplanar with the linker. This demonstrates that two BPBP diradicals communicate through the phenyl ring.

Graphical abstract: 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker

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Publication details

The article was received on 03 Dec 2007, accepted on 03 Mar 2008 and first published on 02 Jul 2008


Article type: Paper
DOI: 10.1039/B718631B
Dalton Trans., 2008, 4482-4487

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    1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker

    A. Rodriguez, G. Fuks, J. Bourg, D. Bourissou, F. S. Tham and G. Bertrand, Dalton Trans., 2008, 4482
    DOI: 10.1039/B718631B

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