Issue 9, 2008
From the journal:

Dalton Transactions

The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate–iron complex with an unusual stannate fragment†

Victor N. Khrustalev,*a   Oleg V. Chernov,bc   Rinat R. Aysin,a   Ivan A. Portnyagin,bc   Mikhail S. Nechaev*bc  and  Sergey S. Bukalova  

* Corresponding authors

a A. N. Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilov Str., 28, Moscow, Russian Federation
E-mail: vkh@xray.ineos.ac.ru
Fax: +7 (0)499 135 5085
Tel: +7 (0)499 135 9343

b A. V. Topchiev Institute of Petrochemical Synthesis of RAS, Leninsky prosp., 29, Moscow, Russian Federation

c Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1/3, Moscow, Russian Federation

Abstract

A new trioxystannate–transition metal complex, {[Li][(Me2NCH2CH2O)3Sn–Fe(CO)4]}2 (3), exhibiting an unusual type of the heteronuclear bonding between heavier Group 14 elements and transition metals, has been synthesised and completely characterised by NMR, Raman and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid state.

Graphical abstract: The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate–iron complex with an unusual stannate fragment

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Article information

DOI
https://doi.org/10.1039/B717197H
Article type
Communication
Submitted
06 Nov 2007
Accepted
03 Jan 2008
First published
04 Feb 2008

Dalton Trans., 2008, 1140-1143

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The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate–iron complex with an unusual stannate fragment

V. N. Khrustalev, O. V. Chernov, R. R. Aysin, I. A. Portnyagin, M. S. Nechaev and S. S. Bukalov, Dalton Trans., 2008, 1140 DOI: 10.1039/B717197H

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