Issue 19, 2008

Titanium and zirconium benzofuranoxides. Crystal structures and catalytic properties

Abstract

Reactions of Ti(OiPr)4 or Zr(OEt)4 with 4 equivalents of 2,3-dihydro-2,2-dimethyl-7-benzofuranol (ddbfoH) in toluene gave neutral complexes that in the solid state are dimers of [Ti(μ-ddbfo)2(ddbfo)6] and [Zr(ddbfo)3(EtOH)(μ-EtO)]2 composition. The former could also be conveniently synthesized in a direct reaction of TiCl4 with ddbfoH. This air-stable aryloxo compound was found to initiate living ring-opening polymerization of lactides affording polyesters with narrow molecular weight distribution. It also catalyzed addition of terminal acetylenes to aryl aldehydes.

Graphical abstract: Titanium and zirconium benzofuranoxides. Crystal structures and catalytic properties

Supplementary files

Article information

Article type
Paper
Submitted
01 Oct 2007
Accepted
22 Feb 2008
First published
25 Mar 2008

Dalton Trans., 2008, 2620-2626

Titanium and zirconium benzofuranoxides. Crystal structures and catalytic properties

K. Krauzy-Dziedzic, J. Ejfler, S. Szafert and P. Sobota, Dalton Trans., 2008, 2620 DOI: 10.1039/B715048B

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