Unlocking the metallaboratrane cage: reversible B–H activation in platinaboratranes†
Abstract
The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt)3}]Cl(Pt→B)8 (mt = methimazolyl, Tol = C6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, viahydride migration to boron and
- This article is part of the themed collection: Collection of articles dedicated to Professor Ken Wade, F.R.S. in celebration of his seventy-fifth birthday